Unprecedented ipso aromatic nucleophilic substitution upon oxidative decarboxylation of tris(p-carboxyltetrathiaaryl)methyl (TAM) radicals: a new access to diversely substituted TAM radicals.

نویسندگان

  • Christophe Decroos
  • Thierry Prangé
  • Daniel Mansuy
  • Jean-Luc Boucher
  • Yun Li
چکیده

A new reaction of oxidative substitution of aromatic carboxyl groups on stable trityl radical derivatives (TAMs) by various nucleophiles is described; it leads to a wide variety of new persistent and diversely substituted TAM radicals.

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عنوان ژورنال:
  • Chemical communications

دوره 47 16  شماره 

صفحات  -

تاریخ انتشار 2011